Electrosynthesis of polyphenylpyrrole coated silver particles at a liquid–liquid interface
نویسندگان
چکیده
This communication reports the production of polyphenylpyrrole coated silver nanoparticles at the liquid/liquid interface by an EC-type mechanism. In the electrochemical step of the reaction N -phenylpyrrole facilitates the transfer of the silver ion from an aqueous to an organic phase. This step is followed by a slow homogeneous electron transfer reaction from the N -phenylpyrrole to the silver ion followed by polymerization and metal cluster growth. 2002 Elsevier Science B.V. All rights reserved.
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